2-Phenylindole → Dimethyl-[(2-phenyl-1H-indol-3-yl)-o-tolylmethyl]-amine

反応式

[C:1]1([C:7]2[NH:8][C:9]3[C:14]([CH:15]=2)=[CH:13][CH:12]=[CH:11][CH:10]=3)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl-].[CH3:17][N+:18]([CH3:27])=[CH:19][C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][C:21]=1[CH3:26]>>[CH3:17][N:18]([CH3:27])[CH:19]([C:15]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[NH:8][C:7]=1[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][C:21]=1[CH3:26]

参加物

反応物 2

HCID 136982-Phenylindole

HCID 21985341(2-Methyl-benzylidene)-dimethylammonium chloride

生成物 1

HCID 10132070Dimethyl-[(2-phenyl-1H-indol-3-yl)-o-tolylmethyl]-amine

実験手順

The preparation was carried out in accordance with general synthesis instructions 4 from 2-phenyl-1H-indole and dimethyl-(2-methyl-benzylidene)-ammonium chloride.

出典と根拠

ORDレコード: ord-eb1b67dc7287425b861bd5d0ec31559a
出典データセット: uspto-grants-2006_08
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07091220B2

反応ノート

読み込み中…