1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(4-hydroxybutyl)-N-methyl- → C4F9SO2N(CH3)(CH2)11OH

関与物質

役割	名称	HCID	仕込み量
反応物	1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(4-hydroxybutyl)-N-methyl-	HCID 69939	—
反応物	11-Bromo-1-undecanol	HCID 74163	—
反応物	1,1,2,2,3,3,4,4,4-nonafluoro-N-methylbutane-1-sulfonamide	HCID 109968	—
反応物	HCID 178418582	HCID 178418582	—
溶媒	Diglyme	HCID 8150	—
生成物	C4F9SO2N(CH3)(CH2)11OH	HCID 131726834	—

反応条件

温度	100 °C

反応手順

C4F9SO2N(CH3)(CH2)11OH was prepared using a procedure similar to that described above for preparing C4F9SO2N(CH3)(CH2)4OH. 175.9 g C4F9SO2NHCH3 and 121.4 g 25% NaOCH3 were reacted to produce a solution of C4F9SO2NNaCH3 in about 100 mL diglyme. This solution was treated with 141 g 11-bromoundecanol (available from Aldrich) and heated at 100° C. for 20 hr to form a heavy precipitate. The reaction was quenched in about 600 mL warm water and the resulting lower layer was stripped at 50° C./0.5 mTorr to leave 269.9 g of C4F9SO2N(CH3)(CH2)11OH, a low-melting solid.

情報源と証拠

DOI	10.6084/m9.figshare.5104873.v1
特許番号	US07361782B2
出典データセット	uspto-grants-2008_04
ORD ID	ord-39c0e5cc0b934026948250077d6b552a
出典メモ	uspto-grants-2008_04