Hydrogen iodide → HCID 22138046、化合物

HRID 901745ノート

反応式

HRID 901745 の反応式
[CH:1]1[C:14]2[CH:13]=[C:12]([C:15]3[CH:16]=[C:17]([C:21]4(O)[C:34]5[CH:33]=[CH:32][CH:31]=[CH:30][C:29]=5[C:28]([C:36]5[CH:41]=[CH:40][CH:39]=[C:38]([C:42]6[C:43]7[C:48]([C:49]8[CH:50]=[CH:51][CH:52]=[CH:53][C:54]=8[CH:55]=6)=[CH:47][CH:46]=[CH:45][CH:44]=7)[CH:37]=5)(O)[C:27]5[C:22]4=[CH:23][CH:24]=[CH:25][CH:26]=5)[CH:18]=[CH:19][CH:20]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.I.[PH2](O)=O>C(O)(=O)C>[CH:1]1[C:14]2[CH:13]=[C:12]([C:15]3[CH:16]=[C:17]([C:21]4[C:22]5[C:27]([C:28]([C:36]6[CH:41]=[CH:40][CH:39]=[C:38]([C:42]7[C:43]8[C:48]([C:49]9[CH:50]=[CH:51][CH:52]=[CH:53][C:54]=9[CH:55]=7)=[CH:47][CH:46]=[CH:45][CH:44]=8)[CH:37]=6)=[C:29]6[C:34]=4[CH:33]=[CH:32][CH:31]=[CH:30]6)=[CH:26][CH:25]=[CH:24][CH:23]=5)[CH:18]=[CH:19][CH:20]=3)[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1

参加物

5

反応物 3

HCID 24841Hydrogen iodideHCID 4124402Phosphinic AcidHCID 22138029HCID 22138029、化合物

生成物 1

HCID 22138046HCID 22138046、化合物

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

反応条件

温度
100 °C

実験手順

9,10-bis(3-(9-Phenanthryl)phenyl)-9,10-dihydroxy-9,10-dihydro-anthracene (5.2 g, 7.3 mmole) was suspended in acetic acid (120 ml). To the resultant suspension, a 57% hydroiodic acid (10 ml, 77 mmole, 10 eq) was added and the obtained mixture was stirred at 100° C. for 6 hours. To the reaction mixture, a 50% aqueous solution of hypophosphorous acid (40 ml) was added. The formed solid was separated by filtration and washed with water, methanol and acetone and a white solid (5.0 g, quant.) was obtained.

後処理

  1. customThe formed solid was separated by filtration
  2. washwashed with water, methanol and acetone
  3. customa white solid (5.0 g, quant.) was obtained

出典と根拠

ORDレコード
ord-0eafd0390dc24f45934cc2b88df8a245
出典データセット
uspto-grants-2008_04
特許番号
US07361796B2

反応ノート

読み込み中…