Octane → 4-Octanol

反応式

[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].CC([OH:17])CCCCCC.CCC(O)CCCCC>>[CH3:1][CH2:2][CH2:3][CH:4]([OH:17])[CH2:5][CH2:6][CH2:7][CH3:8]

参加物

反応物 3

HCID 356Octane

HCID 115273-Octanol

HCID 200832-Octanol

生成物 1

HCID 115154-Octanol

実験手順

A further selective hydroxylation reaction was carried out with the sol-gel-embedded CYP BM-3 on the substrate n-octane. 79% of the precursor were hydroxylated. The regio isomers 2-octanol, 3-octanol and 4-octanol were obtained in a molar ratio of 1:2.1:1.6 (detected by gas chromatography).

後処理

customA further selective hydroxylation reaction

出典と根拠

ORDレコード: ord-20c3b18d9f184c1f8e49d48beccdc67d
出典データセット: uspto-grants-2008_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07364884B2

反応ノート

読み込み中…