HCID 68964218、化合物 → HCID 69117516、化合物
反応式
[CH2:1]([C:4]1[CH:9]=[CH:8][C:7]([Cl:10])=[C:6]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=2[Cl:17])[C:5]=1[OH:18])[CH:2]=[CH2:3]>C(Cl)Cl.CC1C=CC=CC=1[P](C1C=CC=CC=1C)([Pd](Cl)(Cl)[P](C1=C(C)C=CC=C1)(C1C=CC=CC=1C)C1C=CC=CC=1C)C1C=CC=CC=1C>[Cl:17][C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][C:11]=1[C:6]1[C:5]([OH:18])=[C:4]([CH:1]=[CH:2][CH3:3])[CH:9]=[CH:8][C:7]=1[Cl:10]参加物
4
実験手順
Treatment of 3-allyl-2′,6-dichloro-biphenyl-2-ol (6.2 g, 22.2 mmol) in methylene chloride (200 mL) with dichlorobis(acetonitrile)palladium (II) (0.86 g, 3.3 mmol) according to the procedure described for Example 69, Step 5 provided 3.0 g (48%) of 2′,6-dichloro-3-(prop-1-enyl)biphenyl-2-ol as a light yellow oil.