Peracetic Acid → Acetic Acid Hexane

HRID 903108

反応式

HRID 903108 の反応式
[C:1]([O-:4])(=[O:3])[CH3:2].[Tl+].[CH3:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].C(OO)(=O)C.C(C1C=CC(C(C)C(OC)=O)=CC=1)C(C)C>C(O)(=O)C.CCOCC>[C:1]([OH:4])(=[O:3])[CH3:2].[CH3:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

参加物

7

反応物 4

HCID 6585Peracetic AcidHCID 8058Hexane2 回HCID 11247thallium(I) acetateHCID 109101Ibuprofen methyl ester

生成物 1

HCID 22590778Acetic Acid Hexane

試薬・触媒・溶媒 2

HCID 176Acetic Acid溶媒2 回HCID 3283Diethyl Ether溶媒

実験手順

To a solution of 260 mg. (1.0 mmole) of thallium (I) acetate and 24 mg. (0.1 mmole) of hydrated manganese diacetate in 3 ml. of 80 percent aqueous acetic acid and 4.5 ml. of hexane, there was added 0.3 ml. (about 2.0 mmole) of 42 percent peracetic acid solution in acetic acid. After five minutes of stirring there was added 100 mg. (0.5 mmole) of 4-isobutylpropiophenone methyl enol ether in 0.5 ml. of hexane. After stirring the mixture for about thirty-five minutes, a glc analysis of a sample of the reaction mixture indicated that about 89 percent of the enol ether had been converted to methyl 2-(4-isobutylphenyl)propionate, based on the starting wnol ether.

後処理

  1. additionwas added 100 mg
  2. stirringAfter stirring the mixture for about thirty-five minutes

出典と根拠

ORDレコード
ord-d426f638516b408a919da14614283435
出典データセット
uspto-grants-1980_10
特許番号
US04226790

関連ノート

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