2,4,4-Trimethyl-2-pentene → 2-Methyl-2-pentene

HRID 903400

反応式

HRID 903400 の反応式
[CH2:1]=[C:2]1[CH2:7]C[CH2:5][CH2:4][CH2:3]1.[CH2:8]=[C:9]1[CH2:13][CH2:12][CH2:11][CH2:10]1.CC(CCC)=C.CC(=CC(C)(C)C)C.C1(C(CC2C=CC=CC=2)=C)C=CC=CC=1>>[CH3:7][C:2]([CH2:3][CH2:4][CH3:5])=[CH2:1].[CH3:8][C:9](=[CH:10][CH2:11][CH3:12])[CH3:13]

参加物

7

実験手順

Under similar reaction conditions as in Example 5, methylenecyclohexane, methylenecyclopentane, 2-methyl-1-pentene, 2,4,4-trimethyl-2-pentene and 2,3-diphenyl-1-propene underwent the isomerization to the thermodynamically more stable isomers shown in Table 1. The isomerization of 2-methyl-1-pentene afforded only 2-methyl-2-pentene and 4-methyl-2-pentenes were not observed.

出典と根拠

ORDレコード
ord-59e4b36eafe64715b9b486285d51587b
出典データセット
uspto-grants-1980_10
特許番号
US04227028

関連ノート

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