化工社化工社 化学情報印刷レポート · 研究参考用
Hydroquinone → N-(3-(Dimethylamino)-2,2-dimethylpropyl)methacrylamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydroquinone | HCID 785 | — |
| 反応物 | Phosphoric Acid | HCID 1004 | — |
| 反応物 | Butyl Methacrylate | HCID 7354 | — |
| 反応物 | N,N,2,2-Tetramethylpropane-1,3-diamine | HCID 104477 | — |
| 生成物 | N-(3-(Dimethylamino)-2,2-dimethylpropyl)methacrylamide | HCID 3018570 | 60% |
反応手順
426 g (3 mols) of butyl methacrylate, 390 g (3 mols) of N,N,2,2-tetramethylpropane-1,3-diamine, 29.4 g (0.3 mol) of H3PO4, and 2 g of hydroquinone were warmed for 2 hours at 220° C. N-(3-dimethylamino-2,2-dimethylpropyl)-methacrylic acid amide was formed in this way. Yield: 60% (selectivity: 94% calculated on the reacted butyl methacrylate).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04228102 |
| 出典データセット | uspto-grants-1980_10 |
| ORD ID | ord-88a3cdd9cbf546a985bb2883e5f2b385 |
| 出典メモ | uspto-grants-1980_10 |