Ammonia → (2-Nitrophenyl)methanesulfonamide

HRID 904770

反応式

HRID 904770 の反応式
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:10][S:11](Cl)(=[O:13])=[O:12])([O-:3])=[O:2].[NH3:15]>C(OCC)C>[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:10][S:11]([NH2:15])(=[O:13])=[O:12])([O-:3])=[O:2]

参加物

4

反応物 2

HCID 222AmmoniaHCID 4305447(2-nitrophenyl)methanesulfonyl Chloride

生成物 1

HCID 13266249(2-Nitrophenyl)methanesulfonamide

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

To a suspension of 29.4 g of the product of Example 2 in 250 ml of diethyl ether was added 6.5 ml of anhydrous ammonia at 5°-15°. After stirring at 15°-25° for 1 hour, the product was filtered off, washed with ether, and water and oven dried at 60° to give 20.5 g of 2-nitrophenylmethanesulfonamide, m.p.=134°-136°.

後処理

  1. filtrationthe product was filtered off
  2. washwashed with ether, and water and oven
  3. customdried at 60°

出典と根拠

ORDレコード
ord-0962ea6a32954304a1470f3d92c29e71
出典データセット
uspto-grants-1983_12
特許番号
US04420325

関連ノート

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