化工社化工社 化学情報印刷レポート · 研究参考用
1-Butanol → Dibutyl Oxalate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Butanol | HCID 263 | — |
| 反応物 | Butyl nitrite | HCID 10996 | — |
| 反応物 | Butyl Formate | HCID 11614 | — |
| 反応物 | HCID 178418361 | HCID 178418361 | — |
| 反応物 | HCID 178418416 | HCID 178418416 | — |
| 生成物 | Dibutyl Oxalate | HCID 16306 | — |
反応手順
Experiment was run in the same manner as in Example 2 except that the composition of the gaseous starting materials was replaced by 27.9% by volume of carbon monoxide, 6.2% by volume of hydrogen, 1.7% by volume of n-butyl nitrite and 64.2% by volume of nitrogen. As the result, it was found that n-butyl formate was produced in a space time yield of 109 g./l.-catalyst.hr, and small amounts of di-n-butyl oxalate and n-butanol were by-produced.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04420633 |
| 出典データセット | uspto-grants-1983_12 |
| ORD ID | ord-72d869152209498d9e4947f4fb46d16c |
| 出典メモ | uspto-grants-1983_12 |