(1,1'-Biphenyl)-2-ol → (2-Biphenylyloxy)diisobutylaluminum
反応式
C([Al:5]([CH2:10][CH:11]([CH3:13])[CH3:12])[CH2:6][CH:7]([CH3:9])[CH3:8])C(C)C.[C:14]1([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][C:21]=2[OH:26])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C1(C)C=CC=CC=1>[C:20]1([C:14]2[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:25]=[CH:24][CH:23]=[CH:22][C:21]=1[O:26][Al:5]([CH2:6][CH:7]([CH3:8])[CH3:9])[CH2:10][CH:11]([CH3:12])[CH3:13]参加物
4
実験手順
In a manner analogous to that described in Example 1, 16 g of triisobutylaluminum and 13.72 g of 2-phenyl-phenol are reacted in absolute toluene to afford (2-biphenylyloxy)diisobutylaluminum and this is then reacted with 20.52 g of pyridine-N-oxide-2-thiol to yield the title compound. The isolation of the product is carried out in an analogous manner. The yield of (2-biphenylyloxy)bis(2-pyridinethiolato)aluminum N,N'-dioxide, an almost white powder, is 33.4 g, about 92.5% of theory. Upon heating it sinters from about 174° C. and melts at 236°-238° C.