4-(Methylsulfonyl)benzaldehyde → 2-Propanone, 1-[4-(methylsulfonyl)phenyl]-

反応式

CSC1C=CC(C=C([N+]([O-])=O)C)=CC=1.CSC1C=CC([CH2:23][C:24](=[O:26])C)=CC=1.[CH3:27][S:28]([C:31]1[CH:38]=[CH:37][C:34]([CH:35]=O)=[CH:33][CH:32]=1)(=[O:30])=[O:29]>>[CH3:27][S:28]([C:31]1[CH:38]=[CH:37][C:34]([CH2:35][C:24](=[O:26])[CH3:23])=[CH:33][CH:32]=1)(=[O:30])=[O:29]

参加物

反応物 3

HCID 2203764-(Methylsulfonyl)benzaldehyde

HCID 28259171-Methylsulfanyl-4-(2-nitro-propenyl)-benzene

HCID 134577081-[4-(Methylsulfanyl)phenyl]propan-2-one

生成物 1

HCID 233358712-Propanone, 1-[4-(methylsulfonyl)phenyl]-

実験手順

The title compound is prepared by the procedures described in experiments 27a and 27b, replacing 4-methylsulfanyl-benzaldehyde with 4-methanesulfonyl-benzaldehyde (31a).

出典と根拠

ORDレコード: ord-6d1ebca0c83b493c8a531935499cc7af
出典データセット: uspto-grants-2011_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08017608B2

反応ノート

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