Octylamine → HCID 86637176、化合物

HRID 909117

反応式

HRID 909117 の反応式
[C:1]([O:4]CCCOC)(=[O:3])C.[OH:10][CH2:11][CH:12]1[CH2:16][O:15]C(=O)[O:13]1.[CH2:18]([NH2:26])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]>>[OH:10][CH2:11][CH:12]([CH2:16][OH:15])[OH:13].[CH2:18]([NH:26][C:1](=[O:3])[O-:4])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

参加物

4

反応物 3

HCID 8143OctylamineHCID 97944Glycerol carbonateHCID 536841Npc129341

生成物 1

HCID 86637176HCID 86637176、化合物

反応条件

温度
70 °C

実験手順

354 g of methoxypropyl acetate, 237 g (2 moles) of glycerol carbonate (Jeffsol GC from Huntsman; CAS RN: 931-40-8; molecular weight: 118.09) are introduced in succession, under nitrogen, into a three-necked flask equipped with a condenser and an addition funnel. The mixture is stirred at 230 revolutions per minute and heated to 70° C. Then 262.5 g (2.03 moles) of n-octylamine (CAS RN: 11-86-4; molecular weight: 129.25) are added to the reaction mixture in the course of 15 minutes. The reaction is strongly exothermic and the temperature of the reaction mixture reaches approximately 88° C.

後処理

  1. customequipped with a condenser and an addition funnel
  2. customreaches approximately 88° C.

出典と根拠

ORDレコード
ord-bdfbb304a8a44981b4503b9ab65f5667
出典データセット
uspto-grants-2011_09
特許番号
US08017719B2

関連ノート

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