Epichlorohydrin → HCID 23070529、化合物
反応式
[C:1]1([S:7][CH2:8][CH2:9][SH:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:11]([CH:13]1[O:15][CH2:14]1)Cl>>[C:1]1([S:7][CH2:8][CH2:9][S:10][CH2:11][CH:13]([OH:15])[CH2:14][S:10][CH2:9][CH2:8][S:7][C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1参加物
3
実験手順
An excess of 2-(phenylthio)ethanethiol is reacted with epichlorohydrin to form 1,3-bis(2-(phenylthio)ethylthio)propan-2-ol. In the final step, the 1,3-bis(2-(phenylthio)ethylthio)propan-2-ol is reacted with a acryloyl chloride in the presence of a tertiary alkyl amine and dimethylaminopyridine to form 1,3-bis(2-(phenylthio)ethylthio)propan-2-yl acrylate.
出典と根拠
- ORDレコード
- ord-befc9cb1392847fab917f8f4c35d7ec4
- 出典データセット
- uspto-grants-2007_09
- 特許番号
- US07271283B2
反応ノート
読み込み中…