関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1-Octanol | HCID 957 | — |
| 反応物 | Isopropenyl acetate | HCID 7916 | — |
| 反応物 | Sodium Carbonate | HCID 10340 | — |
| 反応物 | Tetrafluoroborate | HCID 26255 | — |
| 反応物 | 2,2-Bis(1-octyloxy)propane | HCID 14118151 | — |
| 反応物 | 1-Octyl isopropenyl ether | HCID 22034535 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | Octyl Acetate | HCID 8164 | — |
反応手順
To a mixture of bis(1,5-cyclooctadiene)iridium tetrafluoroborate [Ir(cod)2]+BF4− (0.01 mmol) and sodium carbonate (0.03 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and isopropenyl acetate (5 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 15 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl isopropenyl ether, 2,2-bis(1-octyloxy)propane, and octyl acetate were produced in yields of 67%, 6%, and 14%, respectively, with a conversion from 1-octanol of 93%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07271297B2 |
|---|
| 出典データセット | uspto-grants-2007_09 |
|---|
| ORD ID | ord-9f95ec1e57fc4021aa36f56642167b1e |
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| 出典メモ | uspto-grants-2007_09 |
|---|
