関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1-Octanol | HCID 957 | — |
| 反応物 | Vinyl Acetate | HCID 7904 | — |
| 反応物 | Octyl Acetate | HCID 8164 | — |
| 反応物 | Sodium Carbonate | HCID 10340 | — |
| 反応物 | 1-(Vinyloxy)octane | HCID 70249 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 1-(1-Octyloxy)ethyl acetate | HCID 22034537 | — |
反応手順
To a mixture of di-1-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and sodium carbonate (0.1 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and vinyl acetate (5 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 2 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl vinyl ether, octyl acetate, and 1-(1-octyloxy)ethyl acetate were produced in yields of 58%, 3%, and 21%, respectively, with a conversion from 1-octanol of 100%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07271297B2 |
|---|
| 出典データセット | uspto-grants-2007_09 |
|---|
| ORD ID | ord-9ae999423ea0441593e4508c7b2c6acf |
|---|
| 出典メモ | uspto-grants-2007_09 |
|---|
