1-Octanol → Octyl Acetate

HRID 916915

反応式

HRID 916915 の反応式
[CH2:1]([OH:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:10](OC=C)(=[O:12])[CH3:11].C(OCCCCCCCC)=C>C1(C)C=CC=CC=1>[C:10]([O:9][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])(=[O:12])[CH3:11]

参加物

5

反応物 3

HCID 9571-OctanolHCID 7904Vinyl AcetateHCID 702491-(Vinyloxy)octane

生成物 1

HCID 8164Octyl Acetate

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
100 °C

実験手順

To a mixture of di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and 4MgCO3—Mg(OH)2-5H2O (0.6 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and vinyl acetate (2 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 2 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl vinyl ether and octyl acetate were produced in yields of 18% and 3%, respectively, with a conversion from 1-octanol of 44%.

後処理

  1. additionwere added

出典と根拠

ORDレコード
ord-8c19adaadfb84c7bb1c8a3506a968cf5
出典データセット
uspto-grants-2007_09
特許番号
US07271297B2

関連ノート

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