関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Vinyl Acetate | HCID 7904 | — |
| 反応物 | Triethylene Glycol | HCID 8172 | — |
| 反応物 | Sodium Acetate | HCID 517045 | — |
| 反応物 | Ethanol, 2-(2-(2-(ethenyloxy)ethoxy)ethoxy)- | HCID 575880 | — |
| 反応物 | Triethylene glycol divinyl ether | HCID 3033992 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | Triethylene glycol monovinyl ether monoacetate | HCID 22034547 | — |
反応手順
To a mixture of di-μ-chlorobis(1,5-cyclooctadiene)diiridium(I) [Ir(cod)Cl]2 (0.01 mmol) and sodium acetate (1.2 mmol) in toluene (2.0 ml),triethylene glycol (1 mmol) and vinyl acetate (4 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 6 hours. The reaction mixture was analyzed by gas chromatography to find that triethylene glycol divinyl ether, triethylene glycol monovinyl ether, and triethylene glycol monovinyl ether monoacetate were produced in yields of 63%, 3%, and 18%, respectively, with a conversion from triethylene glycol of 100%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07271297B2 |
|---|
| 出典データセット | uspto-grants-2007_09 |
|---|
| ORD ID | ord-1d5810fe818a4bc79002725ea7c7a0d3 |
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| 出典メモ | uspto-grants-2007_09 |
|---|
