Phenol → 1-Amino-2-(2',2'-dimethyl-3'-hydroxyhexoxy)-4-hydroxyanthraquinone

HRID 917889

反応式

[CH3:1][C:2]([CH3:10])([CH:5]([OH:9])[CH2:6][CH2:7][CH3:8])[CH2:3][OH:4].[NH2:11][C:12]1[C:25]2[C:24](=[O:26])[C:23]3[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=3)[C:17](=[O:27])[C:16]=2[C:15]([OH:28])=[CH:14][C:13]=1Cl.C1(O)C=CC=CC=1.C(=O)([O-])[O-].[K+].[K+]>CO.CN1CCCC1=O>[NH2:11][C:12]1[C:25]2[C:24](=[O:26])[C:23]3[C:18](=[CH:19][CH:20]=[CH:21][CH:22]=3)[C:17](=[O:27])[C:16]=2[C:15]([OH:28])=[CH:14][C:13]=1[O:4][CH2:3][C:2]([CH3:10])([CH3:1])[CH:5]([OH:9])[CH2:6][CH2:7][CH3:8]

参加物

実験手順

90 parts of 2,2-dimethyl-1,3-hexanediol, 27.3 parts of 1-amino-4-hydroxy-2-chloroanthraquinone, 45 parts of N-methylpyrrolidone, 9.4 parts of phenol and 12 parts of potassium carbonate are heated for 5 hours at 130°C and 8 hours at 140°C under nitrogen. When cold, the mixture is diluted with 140 parts of methanol and filtered. The filtrate is diluted with water. 21 parts of 1-amino-2-(2',2'-dimethyl-3'-hydroxyhexoxy)-4-hydroxyanthraquinone are obtained.

後処理

filtrationfiltered
additionThe filtrate is diluted with water

出典と根拠

ORDレコード: ord-a2e2ad3af67d42e3982cdbe594818557
出典データセット: uspto-grants-1976_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US03968131

反応式

参加物

反応物 4

生成物 1

試薬・触媒・溶媒 2

実験手順

後処理

出典と根拠

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