1-(2,6,6-Trimethyl-1-cyclohexen-1-yl)butane-1,3-dione → HCID 23456997、化合物
反応式
[CH3:1][C:2]1[CH:3]([C:10](=[O:15])[CH2:11][C:12](=[O:14])[CH3:13])[C:4]([CH3:9])([CH3:8])[CH2:5][CH2:6][CH:7]=1.[CH3:16][C:17]1[CH2:22][CH2:21][CH2:20][C:19]([CH3:24])([CH3:23])[C:18]=1[C:25](=[O:30])[CH2:26][C:27](=[O:29])[CH3:28]>>[CH3:1][C:2]1[CH:3]([C:10](=[O:15])[CH2:11][CH:12]([OH:14])[CH3:13])[C:4]([CH3:8])([CH3:9])[CH2:5][CH2:6][CH:7]=1.[CH3:16][C:17]1[CH2:22][CH2:21][CH2:20][C:19]([CH3:23])([CH3:24])[C:18]=1[C:25](=[O:30])[CH2:26][CH:27]([OH:29])[CH3:28]参加物
4
実験手順
By replacing in the above Example 2,6,6-trimethyl-1-[1,3-dioxo-but-1-yl]-cyclohex-2-ene by 2,6,6-trimethyl-1-[1,3-dioxo-but-1-yl]-cyclohex-1-ene the corresponding test samples have an analogous organoleptic note. Similar, but less pronounced effects, were obtained by the use of 2,6,6-trimethyl-1-[3-hydroxy-butan-1-oyl] -cyclohex-2-ene or 2,6,6-trimethyl-1-[3-hydroxy-butan-1-oyl]-cyclohex-1-ene.