Carbon Disulfide → (2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid

HRID 918018

反応式

HRID 918018 の反応式
[CH3:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH2:11].[C:12](=[S:14])=[S:13]>C(O)C>[CH3:1][C:2]1[NH:3][CH:4]=[N:5][C:6]=1[CH2:7][S:8][CH2:9][CH2:10][NH:11][C:12](=[S:13])[SH:14]

参加物

4

反応物 2

HCID 6348Carbon DisulfideHCID 178433288HCID 178433288、化合物

生成物 1

HCID 15566013(2-{[(5-Methyl-1H-imidazol-4-yl)methyl]sulfanyl}ethyl)carbamodithioic acid

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

A solution of 4-methyl-5-((2-aminoethyl)thiomethyl) imidazole (10.2 g) in ethanol (75 ml) was added slowly, with stirring, to carbon disulphide (200 ml). The mixture was set aside overnight at room temperature and the solid formed was collected and recrystallized from aqueous isopropyl alcohol to afford N-[2-((5-methyl-4-imidazolyl)-methylthio)ethyl]dithiocarbamic acid (9.8 g)., m.p. 127°-129°.

後処理

  1. customthe solid formed
  2. customwas collected
  3. customrecrystallized from aqueous isopropyl alcohol

出典と根拠

ORDレコード
ord-abb376b9e5524fe7b2df40e537864ab0
出典データセット
uspto-grants-1976_07
特許番号
US03968227

関連ノート

読み込み中…