Benzene → N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine

HRID 918332ノート

反応式

HRID 918332 の反応式
Cl[C:2]([CH3:17])([CH3:16])[CH2:3][CH2:4][CH2:5][CH:6]([CH3:15])[CH2:7][CH:8]=[CH:9][C:10]([CH3:14])=[CH:11][CH2:12]Br.BrCC=C(C)C=CCC(C)CCC=C(C)C.C1C=CC=CC=1.[CH2:40]([NH:42][CH2:43][CH3:44])[CH3:41]>C(Cl)Cl>[CH2:40]([N:42]([CH2:12][CH:11]=[C:10]([CH3:14])[CH:9]=[CH:8][CH2:7][CH:6]([CH3:15])[CH2:5][CH2:4][CH:3]=[C:2]([CH3:17])[CH3:16])[CH2:43][CH3:44])[CH3:41]

参加物

6

反応物 4

HCID 241BenzeneHCID 8021DiethylamineHCID 5387143211-Chloro-3,7,11-trimethyldodeca-2,4-dienyl bromideHCID 54370561HCID 54370561、化合物

生成物 1

HCID 53837124N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

Five grams of 1 bromo-3,7,11-trimethyldodeca-2,4,10-triene in 25 ml. of benzene is mixed with 4 g. of diethylamine and the mixture stirred for about three hours. Methylene chloride (50 ml.) is added and the mixture washed with dilute sodium hydroxide and then water and evaporated to yield N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine.

後処理

  1. washthe mixture washed with dilute sodium hydroxide
  2. customwater and evaporated

出典と根拠

ORDレコード
ord-fd1ec86af4c24fd3b2e9cc477e948b13
出典データセット
uspto-grants-1976_07
特許番号
US03970704

反応ノート

読み込み中…