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Benzene → Cyclohexyl acetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzene | HCID 241 | — |
| 反応物 | Cyclohexanol | HCID 7966 | — |
| 反応物 | Ethyl Acetate | HCID 8857 | — |
| 触媒 | Ruthenium | HCID 23950 | — |
| 生成物 | Cyclohexyl acetate | HCID 12146 | — |
反応手順
When a benzene solution containing 15 mmols of cyclohexanol, 5 mmols of ethyl acetate and 0.05 mmols of complex 1 was refluxed under argon atmosphere, GC analysis after 28 hrs showed that all of the ethyl acetate disappeared and cyclohexyl acetate was formed as a single product (Table 8, entry 1). 1H NMR and GC-MS of the isolated product were identical to cyclohexyl acetate prepared by refluxing neat acetic anhydride with cyclohexanol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09290441B2 |
| 出典データセット | uspto-grants-2016_03 |
| ORD ID | ord-94025d6f8b0e416db512913c31d4ab47 |
| 出典メモ | uspto-grants-2016_03 |