4-Chloro-4'-nitrobenzophenone → 4-Amino-4'-chlorobenzophenone

HRID 928748

反応式

HRID 928748 の反応式
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]([C:10]2[CH:15]=[CH:14][C:13]([N+:16]([O-])=O)=[CH:12][CH:11]=2)=[O:9])=[CH:4][CH:3]=1.CN1C(C(C2C=CC([N+]([O-])=O)=CC=2)=O)=CN=C1.N1(C2C=CC(CC3C(OC)=NC4C(C=3Cl)=CC(Br)=CC=4C)=CC=2)C=CC=N1>>[NH2:16][C:13]1[CH:14]=[CH:15][C:10]([C:8]([C:5]2[CH:6]=[CH:7][C:2]([Cl:1])=[CH:3][CH:4]=2)=[O:9])=[CH:11][CH:12]=1

参加物

4

反応物 3

HCID 3477714-Chloro-4'-nitrobenzophenoneHCID 86715599HCID 86715599、化合物3 回HCID 86715600(1-Methyl-1H-imidazol-5-yl)(4-nitrophenyl)methanone

生成物 1

HCID 35287064-Amino-4'-chlorobenzophenone

実験手順

The title compound was prepared by using (4-chlorophenyl)(4-nitrophenyl)methanone, (Intermediate 21: step a) in place of (1-methyl-1H-imidazol-5-yl)(4-nitrophenyl)methanone, (Intermediate 20: step b) then following the procedure described for the preparation of (4-aminophenyl)(1-methyl-1H-imidazol-5-yl)methanone (Intermediate 20: step c).

出典と根拠

ORDレコード
ord-f6561176840b424bb343c00588ed5a52
出典データセット
uspto-grants-2016_03
特許番号
US09290476B2

関連ノート

読み込み中…