(2,6-Dimethoxyphenyl)boronic acid → 4-(2,6-dimethoxyphenyl)-9-hydroxypyrrolo[3,4-c]carbazole-1,3(2H,6H)-dione

反応式

[CH3:21][O:22][c:23]1[c:24]([B:31]([OH:32])[OH:33])[c:25]([O:29][CH3:30])[cH:26][cH:27][cH:28]1.[OH:1][c:2]1[cH:3][c:4]2[c:5]3[c:6]4[c:7]([c:8]([I:15])[cH:9][c:10]3[nH:11][c:12]2[cH:13][cH:14]1)[C:16](=[O:20])[NH:17][C:18]4=[O:19]>>[OH:1][c:2]1[cH:3][c:4]2[c:5]3[c:6]4[c:7]([c:8](-[c:24]5[c:23]([O:22][CH3:21])[cH:28][cH:27][cH:26][c:25]5[O:29][CH3:30])[cH:9][c:10]3[nH:11][c:12]2[cH:13][cH:14]1)[C:16](=[O:20])[NH:17][C:18]4=[O:19]

参加物

反応物 2

HCID 2734343(2,6-Dimethoxyphenyl)boronic acid

HCID 118428349-hydroxy-4-iodopyrrolo[3,4-c]carbazole-1,3(2H,6H)-dione

生成物 1

HCID 104753624-(2,6-dimethoxyphenyl)-9-hydroxypyrrolo[3,4-c]carbazole-1,3(2H,6H)-dione

出典と根拠

ORDレコード: ord-b9d07867a15d46349b0ba4d06c7a5d24
出典データセット: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…