Methyl 4-(4-hydroxybenzoyl)benzoate → methyl 4-[(4-hydroxyphenyl)(2,2,6,6-tetramethyltetrahydro-4H-pyran-4-ylidene)methyl]benzoate

反応式

[CH3:20][C:21]1([CH3:30])[O:22][C:23]([CH3:28])([CH3:29])[CH2:24][C:25](=[O:27])[CH2:26]1.[OH:1][c:2]1[cH:3][cH:4][c:5]([C:8](=[O:9])[c:10]2[cH:11][cH:12][c:13]([C:14](=[O:15])[O:16][CH3:17])[cH:18][cH:19]2)[cH:6][cH:7]1>>[OH:1][c:2]1[cH:3][cH:4][c:5]([C:8]([c:10]2[cH:11][cH:12][c:13]([C:14](=[O:15])[O:16][CH3:17])[cH:18][cH:19]2)=[C:25]2[CH2:24][C:23]([CH3:28])([CH3:29])[O:22][C:21]([CH3:20])([CH3:30])[CH2:26]2)[cH:6][cH:7]1

参加物

反応物 2

HCID 10038024Methyl 4-(4-hydroxybenzoyl)benzoate

HCID 118296912,2,6,6-Tetramethyloxan-4-one

生成物 1

HCID 68654824methyl 4-[(4-hydroxyphenyl)(2,2,6,6-tetramethyltetrahydro-4H-pyran-4-ylidene)methyl]benzoate

出典と根拠

ORDレコード: ord-a0a6230f40744b97bddf0f76da506e08
出典データセット: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…