Dichloromethane → 4-[(E)-tert-butoxycarbonylmethylimino]-2,2-dimethyl-butyric acid benzyl ester

反応式

[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6]([CH2:7][NH2:8])=[O:9].[CH2:10]([c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)[O:17][C:18]([C:19]([CH2:20][CH:21]=[O:22])([CH3:23])[CH3:24])=[O:25].[Cl:26][CH2:27][Cl:28]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6]([CH2:7][N:8]=[CH:21][CH2:20][C:19]([C:18]([O:17][CH2:10][c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)=[O:25])([CH3:23])[CH3:24])=[O:9]

参加物

反応物 3

HCID 6344Dichloromethane

HCID 151417Glycine tert-butyl ester

HCID 856568462,2-Dimethyl-4-oxo-butyric acid benzyl ester

生成物 1

HCID 592495724-[(E)-tert-butoxycarbonylmethylimino]-2,2-dimethyl-butyric acid benzyl ester

出典と根拠

ORDレコード: ord-61830f6c9df84ecb9f61239c84353c74
出典データセット: Validation data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…