Adamantanone → N'-(adamantan-2-ylidene)(tert-butoxy)carbohydrazide

HRID 962755

反応式

HRID 962755 の反応式
[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[C:2]1=O)[CH2:8]2.[C:12]([O:16][C:17]([CH3:20])([CH3:19])[CH3:18])(=[O:15])[NH:13][NH2:14]>CCCCCC>[CH:1]12[CH2:10][CH:5]3[CH2:6][CH:7]([CH2:9][CH:3]([CH2:4]3)[C:2]1=[N:14][NH:13][C:12]([O:16][C:17]([CH3:20])([CH3:19])[CH3:18])=[O:15])[CH2:8]2

参加物

4

反応物 2

HCID 64151AdamantanoneHCID 70091tert-Butyl carbazate

生成物 1

HCID 8039095N'-(adamantan-2-ylidene)(tert-butoxy)carbohydrazide

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

実験手順

A hexane solution containing 2-adamantanone (2 g) and tert-butyl carbazate (1.76) was heated to reflux for 3 hours. When the solution cooled, the title compound crystallized and was filtered (3.28 g). M. p. 175-177°.

後処理

  1. temperaturewas heated
  2. temperatureto reflux for 3 hours
  3. temperatureWhen the solution cooled
  4. customthe title compound crystallized
  5. filtrationwas filtered (3.28 g)

出典と根拠

ORDレコード
ord-704dd1d4bb5545e08cbb6cdc82f57b0e
出典データセット
uspto-grants-1998_06
特許番号
US05760059

関連ノート

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