化工社化工社 化学情報印刷レポート · 研究参考用
Ribonolactone → D-Ribonic acid (benzyl 2-benzyloxycarbonylamino-2,6-didesoxy-alpha-D-glucopyranosid-6-yl)-amide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ribonolactone | HCID 111064 | — |
| 反応物 | Benzyl 6-amino-2-benzyloxycarbonylamino-2,6-didesoxy-alpha-D-glucopyranoside | HCID 53644733 | — |
| 溶媒 | 1,4-Dioxane | HCID 31275 | — |
| 生成物 | D-Ribonic acid (benzyl 2-benzyloxycarbonylamino-2,6-didesoxy-alpha-D-glucopyranosid-6-yl)-amide | HCID 86752800 | — |
反応手順
Benzyl 6-amino-2-benzyloxycarbonylamino-2,6-didesoxy-α-D-glucopyranoside (see Ex. 9.C.) and D-ribonic acid g-lactone were reacted as described in Ex. 14.A. and gave D-ribonic acid (benzyl 2-benzyloxycarbonylamino-2,6-didesoxy-α-D-gluco-pyranosid-6-yl)-amide, [α]+81.5° (c 0.2; dioxan), MS: m/z 551.4 ([M+H]+).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05767268 |
| 出典データセット | uspto-grants-1998_06 |
| ORD ID | ord-d5b4f10fe2f6464fa205d7e1f8a3eca5 |
| 出典メモ | uspto-grants-1998_06 |