関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | (3,5-Di-tert-butylphenyl)methanol | HCID 12660843 | — |
| 触媒 | Manganese dioxide | HCID 14801 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | 3,5-Bis(tert-butyl)benzaldehyde | HCID 1268253 | — |
反応手順
To the crude alcohol from above was added MnO2 and CHCl3 (20 mL). The mixture was stirred overnight at 25° C. and filtered, and the organic solvent was evaporated. The crude residue was purified by flash chromatography on silica gel eluting with 1:6 ethyl acetate-hexane to give 0.3 g of 3,5-di-t-butylbenzaldehyde as a white solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05773421 |
|---|
| 出典データセット | uspto-grants-1998_06 |
|---|
| ORD ID | ord-18eedb25bce74f04b968f52632084159 |
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| 出典メモ | uspto-grants-1998_06 |
|---|
