関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Azobisisobutyronitrile | HCID 6547 | — |
| 反応物 | Methyl Methacrylate | HCID 6658 | — |
| 反応物 | Glycidyl methacrylate | HCID 7837 | — |
| 反応物 | 3-Hydroxypropyl methacrylate | HCID 17694 | — |
| 反応物 | 2-(Toluene-4-sulfonyloxy)ethyl methacrylate | HCID 14344249 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | 2-(Toluene-4-sulfonyloxy)ethyl methacrylate 3-hydroxypropyl methacrylate | HCID 86759876 | 65% |
反応手順
In a 500 ml round-bottom flask was placed 0.3 mole of 2-(toluene-4-sulfonyloxy)ethyl methacrylate, 0.22 mole of 3-hydroxypropyl methacrylate, 0.15 mole of methyl methacrylate, 0.3 mole of glycidyl methacrylate, 300 g of tetrahydrofuran (THF), and 0.1 g-3 g of AIBN. The reaction mixture was heated at 60-75° C. for 5-20 hours. The product was precipitated in ethyl ether or n-hexane, filtered and dried to provide poly [2-(toluene-4-sulfonyloxy)ethyl methacrylate/3-hydroxypropyl methacrylate-/methyl methacrylate-/glycidyl methacrylate] represented by the following chemical formula 13, at a yield of 65-70%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06956091B2 |
|---|
| 出典データセット | uspto-grants-2005_10 |
|---|
| ORD ID | ord-a0c7d765352045bc8b57acd008bb8d34 |
|---|
| 出典メモ | uspto-grants-2005_10 |
|---|
