Perfluorooctyl iodide → Dimethyl(octyl)silane

反応式

[SiH:1]([C:4]([C:7]([C:10]([C:13]([C:16]([C:19]([C:22]([C:25](F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)([CH3:3])[CH3:2].C(I)(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F>>[SiH:1]([CH2:4][CH2:7][CH2:10][CH2:13][CH2:16][CH2:19][CH2:22][CH3:25])([CH3:2])[CH3:3]

参加物

反応物 2

HCID 10491Perfluorooctyl iodide

HCID 71346810(Heptadecafluorooctyl)(dimethyl)silane

生成物 1

HCID 57358078Dimethyl(octyl)silane

実験手順

A 10.14 g fraction of HSi(CH3)2C8F17 with a boiling point of 57-59° C. under a pressure of 11 mbar and which comprises, according to 19F NMR, approximately 5% of C8F17I is obtained (yield: 44%).

後処理

customis obtained (yield: 44%)

出典と根拠

ORDレコード: ord-c426141c7571459e9998f17537659c02
出典データセット: uspto-grants-2005_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06958408B2

反応ノート

読み込み中…