(-)-Asparagine → Ammonium Aspartate

HRID 9704

反応式

HRID 9704 の反応式
[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([O-:6])=[O:5].[NH2:10][C@H](C(O)=O)CC(=O)N>>[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([O-:6])=[O:5].[NH4+:10].[NH4+:1]

参加物

3

反応物 2

HCID 6267(-)-AsparagineHCID 5460541l-aspartic acid, sodium salt

生成物 1

HCID 86590683Ammonium Aspartate

反応条件

温度
180 °C

実験手順

The IR spectrum of the product obtained after heating at 180° C. for three hours showed the peaks associated with polymers of aspartate, e.g. at 1391 (carboxylate), 1533 and 1589 (primary amide doublet), and 3300 cm−1 (carboxylate), as well as signals characteristic of asparagine residues, at 1648 cm−1 and 3072 cm−1 (side chain of the —CONH2 R-group) (3300 s, 3072 m, 1648 s, 1589 s, 1533 s, 1391 s, 1196 w). After heating at 220° C. for 4.5 hours, the imide signal at 1704 cm−1 began to emerge, as a result of ammonium aspartate residues being converted to succinimides (3292 s, 3057 w, 2933 w, 1704 sh, 1651 s, 1585 s, 1392 m, 1290 w, 1197 w). After heating at 220° C. for 10 hours, the imide signal at 1704 cm−1 became prominent (FIG. 6) (3300 s, 1704 s, 1664 m, 1530 s, 1383 m, 1355 m, 1296 w, 1194 m).

後処理

  1. customThe IR spectrum of the product obtained
  2. custom(3300 s, 3072 m, 1648 s, 1589 s, 1533 s, 1391 s, 1196 w)
  3. temperatureAfter heating at 220° C. for 4.5 hours

出典と根拠

ORDレコード
ord-2c17127e70e542a9b0255cbe6dba7bc2
出典データセット
uspto-grants-2006_08
特許番号
US07091305B2

関連ノート

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