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Methyl 3-formyl-1H-indole-7-carboxylate → Methyl 3-(hydroxyiminomethyl)indole-7-carboxylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl 3-formyl-1H-indole-7-carboxylate | HCID 762965 | — |
| 反応物 | Hydroxyammonium hydrochloride | HCID 22029257 | — |
| 溶媒 | Dimethylformamide | HCID 6228 | — |
| 生成物 | Methyl 3-(hydroxyiminomethyl)indole-7-carboxylate | HCID 136376389 | 97.4% |
反応手順
5 g of methyl 3-formylindole-7-carboxylate (0.024 mol) are added to a solution of 0.03 mol of hydroxylammonium hydrochloride in dimethylformamide. The reaction mixture is heated at 125° for one hour and subjected to conventional work-up, giving 5.1 g of methyl 3-(hydroxyiminomethyl)indole-7-carboxylate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07312342B2 |
| 出典データセット | uspto-grants-2007_12 |
| ORD ID | ord-35682b06232f4d1fb4ecb9fe1e25772f |
| 出典メモ | uspto-grants-2007_12 |