化工社化工社 化学情報印刷レポート · 研究参考用
Ammonia → 2,4,6-Triphenylpyridine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | Benzaldehyde | HCID 240 | — |
| 反応物 | Acetophenone | HCID 7410 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | 2,4,6-Triphenylpyridine | HCID 136370 | 68% |
反応手順
"Simple aldehydes and ketones without activating groups require mildly forcing conditions and produce the fully aromatic pyridines; accordingly, acetophenone, benzaldehyde, and ammonia in refluxing acetic acid gave a 68% yield of 2,4,6,-triphenylpyridine and a 25% yield of β-phenylpropionophenone."
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04055588 |
| 出典データセット | uspto-grants-1977_10 |
| ORD ID | ord-aa7d96fb12664a28b4538204f2d3b683 |
| 出典メモ | uspto-grants-1977_10 |