化工社化工社 化学情報印刷レポート · 研究参考用
1-Hexanol → Hexyl 2-hydroxy-2-methylpropanoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Hexanol | HCID 8103 | — |
| 反応物 | Propanamide, 2-hydroxy-2-methyl- | HCID 83059 | — |
| 生成物 | Hexyl 2-hydroxy-2-methylpropanoate | HCID 21401559 | 51.8% |
反応手順
A mixture of 20.6 g of α-hydroxy-isobutyramide and 204 g of n-hexyl alcohol was heated in the presence of 0.45 g of PbO for 6 hours at 200° C. in an autoclave. On working up by distillation, 19.5 g (= 51.8 percent of theory) of α-hydroxy-isobutyric acid-n-hexyl-ester were obtained. The amide conversion is 75 percent.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04055590 |
| 出典データセット | uspto-grants-1977_10 |
| ORD ID | ord-cd14d858d59547409c78185637444a00 |
| 出典メモ | uspto-grants-1977_10 |