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Hydrochloric Acid → Methyl 3-(4,6-bis(trichloromethyl)-s-triazin-2-yl)benzoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Trichloroacetonitrile | HCID 11011 | — |
| 反応物 | Benzoic acid, 3-cyano-, methyl ester | HCID 83554 | — |
| 反応物 | Bromhydrol | HCID 166749 | — |
| 生成物 | Methyl 3-(4,6-bis(trichloromethyl)-s-triazin-2-yl)benzoate | HCID 14572905 | — |
反応手順
Methyl 3-cyanobenzoate (70 pw) are mixed with trichloroacetonitrile (376 pw) and aluminum bromide (13.9 pw) as described in Example 1, step 2, hydrogen chloride gas is added, the mixture is allowed to react and the reaction product is separated. Recrystallization from ethanol gives 160 pw=82% of white crystals of methyl 3-(4,6-bis(trichloromethyl)-s-triazin-2-yl)benzoate. M.p.: 115 to 117° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05064959 |
| 出典データセット | uspto-grants-1991_11 |
| ORD ID | ord-75d789af17cf41cba765527cdb44a27a |
| 出典メモ | uspto-grants-1991_11 |