n-octyl (1S,3S,5S)-2-azabicyclo[3.3.0]octane-3-carboxylate → n-Octyl 2-[(Z)-3-methoxycarbonyl-2-propenoyl]-(1S,3S,5S)-2-azabicyclo[3.3.0]octane-3-carboxylate

HRID 974184ノート

反応式

HRID 974184 の反応式
[C@H:1]12[CH2:8][CH2:7][CH2:6][C@H:5]1[CH2:4][C@@H:3]([C:9]([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])=[O:10])[NH:2]2.[C:20]([O:27][CH3:28])(=[O:26])/[CH:21]=[CH:22]\[C:23]([O-])=[O:24]>>[CH3:28][O:27][C:20](/[CH:21]=[CH:22]\[C:23]([N:2]1[C@H:3]([C:9]([O:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])=[O:10])[CH2:4][C@H:5]2[C@@H:1]1[CH2:8][CH2:7][CH2:6]2)=[O:24])=[O:26]

参加物

3

反応物 2

HCID 15924287n-octyl (1S,3S,5S)-2-azabicyclo[3.3.0]octane-3-carboxylateHCID 21768182Mono-methyl maleate

生成物 1

HCID 67925774n-Octyl 2-[(Z)-3-methoxycarbonyl-2-propenoyl]-(1S,3S,5S)-2-azabicyclo[3.3.0]octane-3-carboxylate

実験手順

This compound was obtained analogously to the method described in Example 1 from n-octyl (1S,3S,5S)-2-azabicyclo[3.3.0]octane-3-carboxylate and monomethyl maleate. MS (DCI) =380 (M+1).

後処理

  1. customThis compound was obtained analogously to the method

出典と根拠

ORDレコード
ord-298267a2c2d443bea39670e6c45eae9f
出典データセット
uspto-grants-1991_11
特許番号
US05068242

反応ノート

読み込み中…