化工社化工社 化学情報印刷レポート · 研究参考用
Oxygen → 9H-Fluoren-1-ol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | Propionic Acid | HCID 1032 | — |
| 反応物 | Fluorene | HCID 6853 | — |
| 反応物 | 1,3,5-Trihydroxy-1,3,5-triazinane-2,4,6-trione | HCID 10419723 | — |
| 触媒 | Cobalt diacetate | HCID 6277 | — |
| 触媒 | Manganous Acetate | HCID 12525 | — |
| 生成物 | 9H-Fluoren-1-ol | HCID 96087 | — |
| 生成物 | Fluoreneone | HCID 22281833 | — |
反応手順
A mixture of 1.00 g of fluorene, 0.036 g of hexahydro-1,3,5-trihydroxy-1,3,5-triazine-2,4,6-trione (3% by mole relative to fluorene), 9.0 g of propionic acid, 0.008 g of cobalt(II) acetate.4H2O and 0.008 g of manganese(II) acetate.4H2O was stirred at 120° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 5 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield fluorenon and fluorenol in 86% and 1% yields, respectively, at 99% conversion of fluorene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07091342B2 |
| 出典データセット | uspto-grants-2006_08 |
| ORD ID | ord-357e71c8313b4627985e801cce9d4fe8 |
| 出典メモ | uspto-grants-2006_08 |