化工社化工社 化学情報印刷レポート · 研究参考用
Oxygen → Fluorene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | Fluorene | HCID 6853 | — |
| 反応物 | 1,3,5-Triacetoxy-hexahydro-1,3,5-triazine-2,4,6-trione | HCID 11301124 | — |
| 触媒 | Cobalt diacetate | HCID 6277 | — |
| 触媒 | Manganous Acetate | HCID 12525 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | Fluorene | HCID 6853 | — |
| 生成物 | Fluoreneone | HCID 22281833 | — |
反応手順
A mixture of 1.00 g of fluorene, 0.055 g of 1,3,5-triacetoxy-hexahydro-1,3,5-triazine-2,4,6-trione (3% by mole relative to fluorene), 9.0 g of acetic acid, 0.008 g of cobalt(II) acetate.4H2O and 0.007 g of manganese(II) acetate.4H2O was stirred at 120° C. in an atmosphere of oxygene gas (1 atm=0.1 MPa) for 6 hours. The resulting product in the reaction mixture was analyzed by gas chromatography and was found to yield fluorenon in 93% yield at 99% conversion of fluorene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07091342B2 |
| 出典データセット | uspto-grants-2006_08 |
| ORD ID | ord-580c97f4c2db48c5b59e2f445311d966 |
| 出典メモ | uspto-grants-2006_08 |