Aluminium lithium hydride → HCID 70106539、化合物
反応式
[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]1[O:7][C:8]([CH3:23])=[C:9](/[CH:11]=[CH:12]/[C:13]2[CH:22]=[CH:21][C:16]([C:17](OC)=[O:18])=[CH:15][CH:14]=2)[N:10]=1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1[C:6]1[O:7][C:8]([CH3:23])=[C:9](/[CH:11]=[CH:12]/[C:13]2[CH:14]=[CH:15][C:16]([CH2:17][OH:18])=[CH:21][CH:22]=2)[N:10]=1参加物
3
実験手順
Methyl (E)-4-[2-[2-(2-furyl)-5-methyl-4-oxazolyl]vinyl]benzoate was reduced with lithium aluminum hydride in the same manner as in Reference Example 12 to yield (E)-4-[2-[2-(2-furyl)-5-methyl-4-oxazolyl]vinyl]benzyl alcohol, which was then recrystallized from ethyl acetate-hexane to yield colorless prisms having a melting point of 150°-15° C.
出典と根拠
- ORDレコード
- ord-cbec8ebd8b74491eba7b61712cdc3b23
- 出典データセット
- uspto-grants-1997_03
- 特許番号
- US05614544
反応ノート
読み込み中…