HCID 20201103、化合物 → 4-Methyl-2-(methylthio)thiophen-3-amine

反応式

[CH3:1][S:2][C:3]1[S:4][CH:5]=[C:6]([CH3:11])[C:7]=1[N+:8]([O-])=O>C(OCC)C>[CH3:1][S:2][C:3]1[S:4][CH:5]=[C:6]([CH3:11])[C:7]=1[NH2:8]

参加物

実験手順

6 g (0.22 gram atoms) freshly prepared aluminium amalgam are added over a period of about two minutes to 18.9 g (0.1 mol) of 2-methylthio-4-methyl-3-nitrothiophene dissolved in 200 ml of moist diethylether. The vigorous reaction which sets in after 5-10 minutes is kept under control by cooling the flask in ice.

後処理

customThe vigorous reaction which
customafter 5-10 minutes
temperatureby cooling the flask in ice

出典と根拠

ORDレコード: ord-dfa6b5a73c394992a319395e4b4c1656
出典データセット: uspto-grants-1987_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04666502

反応ノート

読み込み中…

参加物

反応物 1

HCID 20201103HCID 20201103、化合物

生成物 1

HCID 202011094-Methyl-2-(methylthio)thiophen-3-amine

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

後処理

customThe vigorous reaction which
customafter 5-10 minutes
temperatureby cooling the flask in ice

出典と根拠

ORDレコード: ord-dfa6b5a73c394992a319395e4b4c1656
出典データセット: uspto-grants-1987_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04666502

反応ノート

読み込み中…