O-ethylhydroxylamine hydrochloride → 2-[1-(Ethoxyimino)butyl]-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one

HRID 978995

反応式

HRID 978995 の反応式
[C:1]([C:6]1[C:7](=[O:24])[CH2:8][CH:9]([C:13]2[C:18]([CH3:19])=[CH:17][C:16]([CH3:20])=[C:15]([CH2:21][OH:22])[C:14]=2[CH3:23])[CH2:10][C:11]=1[OH:12])(=O)[CH2:2][CH2:3][CH3:4].Cl.[CH2:26]([O:28][NH2:29])[CH3:27]>>[CH2:26]([O:28][N:29]=[C:1]([C:6]1[C:7](=[O:24])[CH2:8][CH:9]([C:13]2[C:18]([CH3:19])=[CH:17][C:16]([CH3:20])=[C:15]([CH2:21][OH:22])[C:14]=2[CH3:23])[CH2:10][C:11]=1[OH:12])[CH2:2][CH2:3][CH3:4])[CH3:27]

参加物

3

反応物 2

HCID 76850O-ethylhydroxylamine hydrochlorideHCID 178450319HCID 178450319、化合物

生成物 1

HCID 1361402292-[1-(Ethoxyimino)butyl]-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one

実験手順

2-[1-(Ethoxyimino)butyl]-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one (51) was prepared from 2-butyryl-3-hydroxy-5-(3-hydroxymethyl-2,4,6-trimethylphenyl)cyclohex-2-en-1-one and ethoxyamine hydrochloride following essentially the same procedure as that described in Example 1, part (iv).

出典と根拠

ORDレコード
ord-bb278c916fdd46438e29e9f6c3ae72f7
出典データセット
uspto-grants-1987_05
特許番号
US04666510

関連ノート

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