Water → HCID 20202084、化合物

HRID 979303ノート

反応式

HRID 979303 の反応式
[CH:1]1[C:14]2[C:5]([O:6][C:7]3[C:12]([N:13]=2)=[CH:11][CH:10]=[CH:9][CH:8]=3)=[CH:4][C:3](=[O:15])[CH:2]=1.[Cl:16]Cl.O>C(O)(=O)C>[Cl:16][C:4]1[C:3](=[O:15])[CH:2]=[CH:1][C:14]2[C:5]=1[O:6][C:7]1[C:12](=[CH:11][CH:10]=[CH:9][CH:8]=1)[N:13]=2

参加物

5

反応物 3

HCID 962WaterHCID 24526ChlorineHCID 114834Phenoxazinone

生成物 1

HCID 20202084HCID 20202084、化合物

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒2 回

実験手順

To a solution of 1.2 g of 3H-phenoxazin-3-one in acetic acid (25 ml) was added K2Cr2O7 (3.7 g). A solution of chlorine in acetic acid was added dropwise to the resulting suspension. After disappearance of the starting material, as monitored by TLC, the reaction mixture was poured into 200 ml of H2O and the resulting precipitate was filtered (1.2 g) and chromatographed on silica gel to yield the title compound.

後処理

  1. filtrationthe resulting precipitate was filtered (1.2 g)
  2. customchromatographed on silica gel

出典と根拠

ORDレコード
ord-9cd040a5fb1546fea51a863e04a35a03
出典データセット
uspto-grants-1987_05
特許番号
US04667032

反応ノート

読み込み中…