関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1,3-Butadiene | HCID 7845 | — |
| 反応物 | N,N,N',N',N'',N''-Hexamethylsilanetriamine | HCID 84795 | — |
| 反応物 | 1-Tris(dimethylamino)silylbuta-1,3-diene | HCID 53996288 | — |
| 溶媒 | O-Xylene | HCID 7237 | — |
| 生成物 | 1-Tris(dimethylamino)silylbut-1-ene | HCID 53651841 | 32% |
反応手順
To a 1 liter autoclave, was added 250 g (1.5 mol) tris(dimethylamino)silane, 100 g xylene, 168 g (3.1 mol) 1,3-butadiene and 200 ppm RhCl(PPh3)3 (0.45 g) as the catalyst. After the autoclave was secured, the reaction was heated to 125° C. for four hours. The reactor was then cooled to room temperature. GC and GC/MS revealed that the major product formed was 1-tris(dimethylamino)silylbuta-1,3-diene in 65% yield. 1-tris(dimethylamino)silylbut-1-ene was also formed in 32% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US04668812 |
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| 出典データセット | uspto-grants-1987_05 |
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| ORD ID | ord-658a7fba799344e9b05c5c355b45109d |
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| 出典メモ | uspto-grants-1987_05 |
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