Ammonium Hydroxide → 6-Amino-5-nitro-1-tetralone

HRID 979812ノート

反応式

HRID 979812 の反応式
C([NH:4][C:5]1[C:6]([N+:16]([O-:18])=[O:17])=[C:7]2[C:12](=[CH:13][CH:14]=1)[C:11](=[O:15])[CH2:10][CH2:9][CH2:8]2)(=O)C.[OH-].[NH4+]>Cl>[NH2:4][C:5]1[C:6]([N+:16]([O-:18])=[O:17])=[C:7]2[C:12](=[CH:13][CH:14]=1)[C:11](=[O:15])[CH2:10][CH2:9][CH2:8]2

参加物

4

反応物 2

HCID 14923Ammonium HydroxideHCID 140052246-Acetamido-5-nitro-1-tetralone

生成物 1

HCID 140052266-Amino-5-nitro-1-tetralone

試薬・触媒・溶媒 1

HCID 313Hydrochloric Acid溶媒

実験手順

The product from Example 81 (1 g) was treated with 6N hydrochloric acid (30 ml) at reflux for 2 hours and the reaction cooled then basified with ammonium hydroxide. The desired product was filtered, washed and dried.

後処理

  1. temperatureat reflux for 2 hours
  2. temperaturethe reaction cooled
  3. filtrationThe desired product was filtered
  4. washwashed
  5. customdried

出典と根拠

ORDレコード
ord-6c32b94f6dd94432b0b222811c94b446
出典データセット
uspto-grants-1987_01
特許番号
US04634705

反応ノート

読み込み中…