化工社化工社 化学情報印刷レポート · 研究参考用
Sodium Sulfite → 4-Hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium Sulfite | HCID 24437 | — |
| 反応物 | Neodecanoyl chloride | HCID 94502 | — |
| 反応物 | 2,5-Dimethylhexane 2,5-dihydroperoxide | HCID 520470 | — |
| 生成物 | 4-Hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate | HCID 86118590 | 55.1% |
反応手順
Reacting neodecanoyl chloride with 2,5-dimethyl-2,5-dihydroperoxyhexane followed by reducing the intermediate product with a buffered sodium sulfite solution employing the same procedure as used in preparation of C-5 resulted in the preparation of 4-hydroxy-1,1,4,4-tetramethylbutyl peroxyneodecanoate. The liquid product had an assay of 91.7% and was obtained in a corrected yield of 55.1%. An infrared spectrum of the product showed a broad OH band centered at 3300 to 3500 cm-1.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04634753 |
| 出典データセット | uspto-grants-1987_01 |
| ORD ID | ord-ae8009b164e641cdab3357e777a547e8 |
| 出典メモ | uspto-grants-1987_01 |