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2-Methyl-1-pentanol → Magnesium 2-methyl-1-pentyloxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Methyl-1-pentanol | HCID 7745 | — |
| 反応物 | Potassium t-amylate | HCID 23683543 | — |
| 反応物 | HCID 178448199 | HCID 178448199 | — |
| 溶媒 | Cyclohexane | HCID 8078 | — |
| 溶媒 | Heptane | HCID 8900 | — |
| 生成物 | Magnesium 2-methyl-1-pentyloxide | HCID 86741193 | — |
反応手順
To a volume of 10 ml of 1.156 Molar n-butyl-sec-butyl-magnesium (11.56 mmoles) there is added 1.43 ml (11.56 mmoles) of 2-methyl-1-pentanol, diluted to 5 ml with heptane. Then, 0.6 ml of 0.99 Molar (0.59 mmoles) of potassium tert-amylate in cyclohexane solution is added, followed by an additional 1.43 ml of 2-methyl-1-pentanol (11.56 mmoles). A pale yellow, clear, slightly viscous solution of magnesium 2-methyl-1-pentyloxide is obtained. No excess of 2-methyl-1-pentanol is added as in comparative Example I(a).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04634786 |
| 出典データセット | uspto-grants-1987_01 |
| ORD ID | ord-7f1344ec469a479d81a74bc173a04999 |
| 出典メモ | uspto-grants-1987_01 |