1-Methyl-4-Prop-1-En-2-Ylcyclohexene → N-CBZ-S-(1-(4-methylcyclohex-3-enyl)isopropyl)-L-cysteine methyl ester

HRID 980525

反応式

HRID 980525 の反応式
[CH3:1][O:2][C:3](=[O:18])[C@H:4]([CH2:16][SH:17])[NH:5][C:6]([O:8][CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)=[O:7].[CH3:19][C:20]1[CH2:25][CH2:24][CH:23]([C:26]([CH3:28])=[CH2:27])[CH2:22][CH:21]=1>CCOCC>[CH3:1][O:2][C:3](=[O:18])[C@H:4]([CH2:16][S:17][C:26]([CH:23]1[CH2:24][CH2:25][C:20]([CH3:19])=[CH:21][CH2:22]1)([CH3:28])[CH3:27])[NH:5][C:6]([O:8][CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)=[O:7]

参加物

4

反応物 2

HCID 223111-Methyl-4-Prop-1-En-2-YlcyclohexeneHCID 11391550Methyl (2R)-2-{[(benzyloxy)carbonyl]amino}-3-sulfanylpropanoate

生成物 1

HCID 131715037N-CBZ-S-(1-(4-methylcyclohex-3-enyl)isopropyl)-L-cysteine methyl ester

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

The ether is prepared from N-CBZ-L-cysteine methyl ester and α-limonene in a manner similar to that described in Example 1B. The product can be characterized by NMR spectroscopy.

出典と根拠

ORDレコード
ord-31fa0c532fba4f90b398678e9c54bf38
出典データセット
uspto-grants-1987_01
特許番号
US04638071

関連ノート

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