Acetyl chloride → HCID 20069224、化合物

反応式

[C:1]1([CH:7]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[CH:15]=[CH2:16])[CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1(C(C2C=CC=CC=2)C)C=CC=CC=1.C(Cl)(=[O:33])C>>[C:1]1([CH:7]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[C:15](=[O:33])[CH3:16])[CH3:8])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

参加物

反応物 3

HCID 6367Acetyl chloride

HCID 119181,1-Diphenylethane

HCID 21696373HCID 21696373、化合物

生成物 1

HCID 20069224HCID 20069224、化合物

実験手順

They can be prepared by a variety of chemical synthetic manners, and for example, phenyl-(vinylpheny)ethane may be prepared by reacting diphenylethane with acetyl chloride in the presence of a Friedel-Crafts catalyst to form phenyl(acetylphenyl)ethane, reducing the latter with sodium boron hydrine or the like, and dehydrating it. Phenyl(isopropenylphenyl)ethane can be prepared by reacting phenyl(formylphenyl)ethane with a Grignard reagent such as methylmagnesium iodide, and carrying out dehydration.

後処理

customThey can be prepared by a variety of chemical synthetic manners

出典と根拠

ORDレコード: ord-c89ac98360e843c99d77f82aa1d105c1
出典データセット: uspto-grants-1991_02
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04994539

反応ノート

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